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The use of nanoparticles is set to escalate and the market has the potential to increase dramatically over the next ten years as more uses for these materials are developed and commercialized. Eventually, nanomaterials are likely to affect nearly every industry in every region in the world, including the least developed regions. In fact, there is considerable optimism that nanomaterials will be instrumental in addressing some of the developing world’s most pressing concerns.

Table Of Contents

Nanomaterials for Solar Cells, Displays, Sensors, Lighting and RFID Market Analyses and Driving Forces
TABLE OF CONTENTS

Chapter 1 Introduction 1-1

Chapter 2 Nanomaterial Properties and Fabrication 2-1

2.1 Introduction 2-1
2.2 Materials Used In Nanotechnology 2-4
2.2.1 Fullerenes 2-4
2.2.1.1 Buckyballs - Buckminsterfullerene 2-7
2.2.1.2 Buckytubes - Nanotubes 2-8
2.2.1.3 Fabrication Of Nanotubes 2-10
2.2.2 Nanoparticles 2-15
2.2.2.1 Introduction 2-15
2.2.2.2 Fabrication Of Nanoparticles 2-20

Chapter 3 Developments In Nanomaterial-Based Solar Cells 3-1

3.1 Introduction 3-1
3.2 Nanomaterials As Solar Conversion 3-3
3.2.1 Inorganic Nanocrystals 3-11
3.2.1.1 Silicon Nanoparticles 3-11
3.2.1.2 Nobel Metals 3-12
3.2.1.3 Multimetal-Dielectric Nanocomposites 3-14
3.2.2 CdSe And CdTe Nanorods 3-17
3.2.3 Quantum Dots 3-19
3.2.4 Nanocomposite - Quantum Dot Combination 3-22
3.2.5 Quantum Wells 3-23
3.2.6 Organic Polymers - Fullerenes 3-25
3.2.7 Ionic Organic Polymers 3-27
3.2.8 CIGS 3-27
3.2.9 Dye-Sensitized Solar Cells 3-33
3.3 Nanomaterials As Modified Electrodes 3-40
3.3.1 Nanowires 3-40
3.3.1.1 ZnO Nanowires 3-40
3.3.1.2 InP Nanowires 3-40
3.3.2 Carbon Nanotubes 3-41
3.3.2.1 Defected Carbon Nanotubes 3-47
3.3.2.2 Silicon Nanotubes 3-50
3.3.2.3 Titania Nanotubes 3-51
3.4 Theoretical Work 3-52

Chapter 4 Nanomaterials for Displays 4-1

4.1 Introduction 4-1
4.2 LCDs 4-1
4.3 Electrophoretic/Electrochromic Displays 4-11
4.3.1 Electrophoretic Displays 4-11
4.3.2 Electrochromic Displays 4-13
4.4 OLEDs 4-10
4.5 Backplanes 4-26

Chapter 5 Nanomaterials for Sensors 5-1

5.1 Introduction 5-1
5.2 NanoChemical Sensors 5-3
5.3 NanoBio/NanoMed Sensors 5-5
5.5 Military and Homeland Defense Applications 5-10
5.5 Quantum Dot Sensors 5-13
5.6 Others 5-14

Chapter 6 Nanomaterials for Lighting 6-1

6.1 Introduction 6-1
6.2 High-efficiency Organic LEDs (OLEDs) 6-2
6.3 Electroluminescent Devices 6-6

Chapter 7 Nanomaterials for RFIDs 7-1

7.1 Introduction 7-1
7.2 RFID Devices 7-1
7.3 Current Uses 7-3
7.4 Uses For Potential Strong Growth 7-4

Chapter 8 Nanomaterials for Semiconductors 8-1

8.1 Nanotubes For Integrated Circuits 8-1
8.2 Slurries 8-4
8.3 Lithography 8-6
8.3.1 Photoresist 8-6
8.3.2 DUV Immersion Liquid 8-9

Chapter 9 Nanomaterial Deposition Trends 9-1

9.1 Vapor Phase 9-1
9.2 Electrodeposition 9-3
9.3 Spray Pyrolysis 9-5
9.4 Laser Pyrolysis 9-5
9.5 Screen Printing 9-6
9.6 Small Nanoparticle Deposition 9-9
9.7 Slurry Spraying And Meniscus Coating Of Precursors 9-10
9.8 Ink-Jet 9-14
9.9 Dip Pen Nanolithography 9-15

Chapter 10 Analysis and Forecast of Nanomaterials for Electronics 10-1

10.1 Driving Forces 10-1
10.2 Analysis of Nanomaterial Markets for All Applications - 2008-2015 10-14
10.3 Analysis of Nanomaterial Markets for Electronics by Material 10-19
10.3.1 Analysis of Nanomaterial Markets for Nanocomposites 10-22
10.3.2 Analysis of Nanomaterial Markets for Nanoparticles 10-24
10.3.3 Analysis of Nanomaterial Markets for Nanowires 10-26
10.3.4 Analysis of Nanomaterial Markets for Fullerenes 10-28
10.3.5 Analysis of Nanomaterial Markets for Slurries 10-29
10.3.6 Analysis of Nanomaterial Markets for Precursors 10-30
10.3.7 Analysis of Nanomaterial Markets for Catalysts 10-31
10.3.8 Analysis of Nanomaterial Markets for Coatings 10-33
10.3.9 Analysis of Nanomaterial Markets for Designer Materials 10-34
10.3.10 Analysis of Nanomaterial Markets for Engineered
Substrates 10-35
10.4 Analysis of Nanomaterial Markets for Electronics by
Application 10-37
10.4.1 Analysis of Nanomaterial Markets for Lighting 10-39
10.4.2 Analysis of Nanomaterial Markets for Displays 10-40
10.4.3 Analysis of Nanomaterial Markets for RFID 10-41
10.4.4 Analysis of Nanomaterial Markets for Sensors 10-43
10.4 5 Analysis of Nanomaterial Markets for Solar Cells 10-46
10.4.6 Analysis of Nanomaterial Markets for Semiconductors 10-53


LIST OF FIGURES

2.1 Surface Area Comparison Of Nanomaterials 2-3
2.2 Typical Structures Of Fullerene 2-5
2.3 Arc-Electric Discharge Fabrication Method 2-12
2.4 CVD Fabrication Method 2-14
2.5 Solutions Of Monodisperse CCSE Nanocrystals 2-19
2.6 Nanoparticles By Sol Gel Technique 2-24
2.7 Nanoparticles By Physical Vapor Synthesis 2-25
3.1 Amorphous Silicon Solar Film Diagram 3-5
3.2 CIGS Solar Film Roll-To-Roll Diagram 3-6
3.3 CdTe Solar Film Diagram 3-8
3.4 Conversion Of Light Via Plasmons 3-13
3.5 Solar Emission From Nanoparticles 3-16
3.6 Energy Levels Of CdSe Quantum Dots 3-21
3.7 Schematic Diagram Of Quantum Well Solar Cell 3-24
3.8 CIGS Module Cross Section 3-29
3.9 How Dye-Sensitized Solar Cells Work 3-34
3.10 Dye-Sensitized Solar Cells Components 3-39
3.11 Electron Transport Across Nanostructured Semiconductor Films 3-43
3.12 Electron Transport In Nanoparticle Solar Cell 3-45
3.13 Carbon Nanotubes In Organic Solar Cells 3-48
4.1 Nanoink's Dip Pen Nanolithography Technology 4-5
4.2 Inkjet Printing Of A Plastic Transistor 4-17
4.3 Vials Of Fluorescent CdSe QDS Dispersed In Hexane 4-21
4.4 A QD-LED Device 4-23
5.1 Carbon Nanotube Biosensor 5-8
5.2 Sensors In Defense Applications 5-12
7.1 EPC RFID Tag 7-5
9.1 Vapor Phase Deposition Of Nanomaterials 9-2
9.2 Electrodeposition Of Nanomaterials 9-4
9.3 Spray Pyrolysis Deposition Of Nanomaterials 9-7
9.4 Screen Printing Of Nanomaterials 9-8
10.1 Worldwide Solar Cell Production 10-51
10.2 Nanomaterial Share By Technology - 2010 And 2015 10-54


LIST OF TABLES

4.1 Proven Inks/Substrates 4-6
10.1 A Selection Of Current And Future Applications Using Nanoparticles 10-11
10.2 NNI Budget 10-17
10.3 NNI Budget History 10-18
10.4 Nanoelectronic Applications By Industry 10-20
10.5- Worldwide Nanomaterial Markets For Electronics By Material. 10-21
10.6 Worldwide Nanomaterial Markets For Electronics By Application 10-38
10.7 Worldwide Thin Film Solar Cell Forecast 10-50


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