Diamond, Diamond-like and CBN Films and Coating Products

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Diamond, Diamond-like and CBN Films and Coating Products

Report price : $ 4 850
Publication date : August 2007

This report: Provides a technological overview of the various diamond, diamond-like, and CBN thin films and coated products, their production technologies, and status of the current and emerging technologies; Identifies and describes existing and new applications; Identifies the technological and business issues related to development and commercial production; Determines the current size and future growth of the U.S. and worldwide markets; Analyzes domestic and foreign competition among companies and their product market segments; Identifies and profiles U.S. and foreign producers and those entities involved in the development of diamond, diamond-like, and CBN films and products; Conducts a patent analysis to evaluate the international competition in the issuance of patents between countries and companies.

INTRODUCTION STUDY GOALS AND OBJECTIVES CONTRIBUTION OF THE STUDY FORMAT AND SCOPE METHODOLOGY AND INFORMATION SOURCES INTENDED AUDIENCE ANALYST CREDENTIALS RELATED BCC PUBLICATIONS BCC ONLINE SERVICES DISCLAIMER

EXECUTIVE SUMMARY

SUMMARY TABLE GLOBAL MARKET FOR DIAMOND AND

DIAMOND-LIKE COATINGS, THROUGH 2012 ($ MILLION)

SUMMARY FIGURE GLOBAL MARKET FOR DIAMOND AND

DIAMOND-LIKE COATINGS, 2006-2012 ($ MILLION)

TECHNOLOGY REVIEW HISTORICAL PERSPECTIVE EARLY WORK IN DIAMOND SYNTHESIS Study by the Foreign Applied Sciences Assessment Center The Validity of Early Work Later Advances in Diamond Deposition TYPES OF DIAMOND AND DIAMOND-LIKE FILMS/COATINGS DIAMOND COATINGS AND FILMS

TABLE 1 PROPERTIES OF POLYCRYSTALLINE DIAMOND AND DIAMOND-LIKE FILMS COMPARED TO NATURAL DIAMOND

DIAMOND-LIKE AND SIMILAR MATERIAL COATINGS AND

FILMS

Diamond-like Hydrocarbons (DLHC or A:CH)

Diamond-Like Carbon (DLC or A:C-C)

Diamond-Like Nanocomposite (DLN)

Cubic Boron Nitride (CBN)

COMPETING TYPES OF MATERIALS

PROPERTIES OF DIAMOND/DIAMOND-LIKE COATINGS AND

FILMS

CHARACTERISTICS OF DIAMOND FILMS

TABLE 2 CHARACTERISTICS OF CVD DIAMOND FILM

TABLE 3 PROPERTIES OF DIAFILM OPTICAL-GRADE

POLYCRYSTALLINE DIAMOND MATERIAL SUPPLIED BY HARRIS INTERNATIONAL

TABLE 4 PROPERTIES OF CVD POLYCRYSTALLINE DIAMOND MATERIAL FOR THERMAL MANAGEMENT SUBSTRATES

TABLE 4 (CONTINUED)

DIAMOND-LIKE COATINGS AND FILMS

TABLE 5 COMPARISON OF PROPERTIES: NATURAL, PCD/CVD DIAMONDS, AND DIAMOND-LIKE CARBON FILMS

ADVANTAGES AND DISADVANTAGES OF CVD DIAMOND

TABLE 6 ADVANTAGES OF CVD DIAMOND

TABLE 7 DISADVANTAGES OF CVD DIAMOND

PRODUCTION TECHNIQUES

DIAMOND FILMS

TABLE 8 CURRENT PROCESSING TECHNOLOGIES FOR THIN AND THICK DIAMOND FILMS

Chemical Vapor Deposition (CVD) Process

Chemical Vapor … (Continued)

Plasma CVD

TABLE 9 PLASMA-ENHANCED CHEMICAL VAPOR DEPOSITION (PECVD) PROCESSES FOR DIAMOND FILM GROWTH

DC Plasma Method

RF Induction Plasma

Microwave Plasma Torch

Plasma Process Comparisons

Other Plasma-Enhanced Techniques

Nonplasma Processes

TABLE 10 NONPLASMA DEPOSITION PROCESSES FOR DIAMOND FILM GROWTH (MICRONS/HR)

Hybrid Processes

Vapor-Liquid-Solid (VLS) Growth

Using Buckyballs to Produce Diamond Films

Physical Vapor Deposition Processes

Basic Processes

TABLE 11 DEPOSITION DATA FOR DLC, BN, AND RELATED COMPOSITES

TABLE 11 (CONTINUED)

Ion Plating

RF Plasma Deposition

Interactive Laser Techniques

QQC Process

New Developments in Diamond Films and Coatings

Improvements in Existing Technologies

Oriented Diamond Films on Si

Substrate

Diamond Synthesized on Glassy and

Oxide Substrates

Diamond Growth on Iron and Steel

Substrate

Models Simulate Diamond Deposition

by DC Arc Jet

Diamond Nucleation by Gas Phase

Seeding

The Influence of Ion Bombardment on

Diamond Film Orientation During

MPCVD

Nucleation and Early Growth of CVD

Diamond on Silicon Nitride

Development of Grinding Technology

for Diamond Film Coated Cutting

Tool

Refinement of QQC Process

New Technologies

Using Buckyballs to Produce Diamond

Films

Micropatterns by ECR Oxygen Plasma

An Effective System for Diamond

Coating Deposition

Diamond Synthesized High-Pressure,

Hot-Filament CVD

Energy Efficient Microwave Diamond

Film Deposition System

Recent U.S. Diamond Coating Technology Patents

Recent U.S. Diamond …(Continued)

Diamond-Like Materials and Coatings

TABLE 12 CURRENT PROCESSING TECHNOLOGIES FOR DIAMOND-LIKE THIN FILMS

RF Plasma-Assisted CVD

Direct Ion Beam Deposition

Dual Ion Beam Deposition Configuration

Plasma Injection—CVD Method

Hot-Filament Cathode Deposition System

Filtered Cathode Arc Source

New Developments in Diamond-Like Materials and

Coatings

Improvements in Existing Technologies

Hot-Filament CVD Produces Ultrahard

Carbon Nitride Film

Carbon Nitride Thin Films by ECR

Plasma

New Technologies

Metalorganic CVD of Ru-Doped DLC

Argonne Develops Superlow-Friction

DLC Films

Cathodic Arc Deposits Amorphous

Diamond

Arc Method Deposits Amorphous

Diamond

Highly Adhesive DLC Using Ion Beam

Mixing Methods

Recent U.S. Diamond-Like Coating Patents

CBN Coatings

TABLE 13 CURRENT PROCESSING TECHNOLOGIES FOR CBN FILMS

New Developments in CBN Coatings

Improvement in Existing Technologies

Rectifying Characteristics of

Tungsten/P-Type CBN Films

Crystalline Boron Nitride Films

Cathodic Arc Evaporation and

Magnetron Sputtering Deposited

BN Films

Improved Adhesion of Sputtered CBN

Films

Hard Wear-Resistant Layer Formation

in CBN Systems

New Technologies

CBN Films in a Two-Step Process

CBN Films Using Mass-Selected Ion

Beam Deposition

CBN Film Synthesized by Plasma-Jet

CVD

Recent U.S. Cubic Boron Nitride Coating Patents

Recent U.S. …(Continued)

APPLICATIONS FOR DIAMOND, DIAMOND-LIKE, AND CBN MATERIAL COATINGS AND FILMS

TABLE 14 CVD DIAMOND AND DLC APPLICATIONS

TABLE 14 (CONTINUED)

DIAMOND FILMS AND COATINGS

TOOLS AND WEAR RESISTANT PARTS

TABLE 15 PROPERTIES OF DIAMOND TOOL MATERIALS, C-2 TUNGSTEN CARBIDE, AND SILICON NITRIDE

AUDIO SPEAKER DIAPHRAGMS

HEAT SINKS AND THERMAL MANAGEMENT SOLUTIONS

Diamond Film Substrate Application Size Potentials

Diamond Film Substrate …(Continued)

PRINT/RECORD HEADS AND HARD DISKS

SEMICONDUCTORS

TABLE 16 COMPARISON OF PROPERTIES OF DIAMOND AND OTHER SEMICONDUCTOR MATERIALS

High-Power Transistors

High-Performance (Rapid Response) Transistors

High-Temperature Transistors

Radiation-Hard Transistors

Reliable Electronics

SURFACE ACOUSTIC WAVE, SENSOR, AND OTHER

ELECTRONIC DEVICES

Surface Acoustic Wave Devices

Sensors

Thermistors

Piezoresistive Pressure Sensors

Micro-Electromechanical Systems

Other Electronic Devices

High-Power Microwave Tubes

High-Voltage Electronics

OPTICAL AND OPHTHALMIC COATINGS

TABLE 17 FIGURES OF MERIT FOR THERMAL STRESS RESISTANCE

Optical and Ophthalmic Coatings (Continued)

FIELD EMISSION DEVICES

MEDICAL DEVICES

Surgical and Medical Tools

Implants

CONSUMER APPLICATIONS

SPORTS EQUIPMENT

CORROSION-, WEAR-, AND TEMPERATURE-RESISTANT

APPLICATIONS

OTHER DIAMOND FILM APPLICATIONS

X-Ray Masks for Advanced Projection Photolithography

X-Ray Targets

Knives and Cutting Blades

DIAMOND-LIKE MATERIALS AND COATINGS

TABLE 18 DIAMOND-LIKE FILM APPLICATIONS

TABLE 18 (CONTINUED)

TABLE 19 CURRENT APPLICATIONS FOR HYDROGENATED DLC

TOOLS AND WEAR-RESISTANT PARTS

COMPUTER HARD DISKS

ELECTRONICS APPLICATIONS

OPTICAL APPLICATIONS

MEDICAL IMPLANTS

CONSUMER APPLICATIONS

WEAR- AND CORROSION-RESISTANT APPLICATIONS

OTHER APPLICATIONS

CBN COATINGS

CBN COATINGS (CONTINUED)

MARKETS SUMMARY

FIGURE 1 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE

COATINGS, 2006-2012 ($ MILLIONS)

MARKET SEGMENTS

APPLICATION SEGMENTS

TABLE 20 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE COATINGS BY APPLICATION SEGMENT, THROUGH 2012 ($ MILLION)

FIGURE 2 DIAMOND AND DIAMOND-LIKE COATING MARKET SHARES BY APPLICATION, 2006 VS. 2012 (PERCENT OF TOTAL MARKET)

FIGURE 2 (CONTINUED)

Tools and Wear-Resistant Parts

TABLE 21 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE FILM IN TOOLS AND WEAR-RESISTANT PARTS, THROUGH 2012 ($ MILLIONS)

Tools

TABLE 22 GLOBAL CONSUMPTION OF DIAMOND AND DIAMONDLIKE COATINGS FOR CUTTING TOOL INSERTS, 2006 ($ MILLION)

TABLE 23 PROJECTED CONSUMPTION OF DIAMOND AND DIAMOND-LIKE COATINGS FOR CUTTING TOOL INSERTS, THROUGH 2012 ($ MILLIONS)

Wear-resistant Parts

TABLE 24 PROJECTED CONSUMPTION OF DIAMOND AND DIAMOND-LIKE COATINGS FOR WEAR-RESISTANT PARTS, THROUGH 2012 ($ MILLIONS)

Audio Speakers

TABLE 25 GLOBAL MARKET FOR DIAMOND IN HIGH-END AUDIO SPEAKER APPLICATIONS, THROUGH 2012 ($ MILLIONS)

Thermal Management Devices

TABLE 26 GLOBAL MARKET FOR DIAMOND IN THERMAL MANAGEMENT APPLICATIONS, THROUGH 2012 ($ MILLIONS)

Computer Hard Disk and Print/Recording Heads

TABLE 27 GLOBAL MARKET FOR DIAMOND LIKE COATINGS IN PRINT/RECORD HEADS AND HARD DISKS, THROUGH 2012 ($ MILLIONS)

Semiconductors

Surface Acoustic Wave (SAW), Sensors, and Other

Electronic Devices

TABLE 28 GLOBAL MARKET FOR DIAMOND MATERIALS USED IN SAW FILTERS AND OTHER ELECTRONIC DEVICES, THROUGH 2012 ($ MILLIONS)

Surface Acoustic Wave Devices

TABLE 29 GLOBAL SALES OF 2.5G/3G MOBILE HANDSETS, THROUGH 2012

TABLE 30 GLOBAL MARKET FOR DIAMOND MATERIALS USE DIN SAW FILTERS, THROUGH 2012 ($ MILLIONS)

Sensors

TABLE 31 GLOBAL MARKET FOR DIAMOND MATERIALS USED IN SENSOR APPLICATIONS, THROUGH 2012 ($ MILLIONS)

Optical Applications

TABLE 32 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE OPTICAL AND OPHTHALMIC COATINGS, THROUGH 2012 ($ MILLIONS)

Cold Cathodes and Flat-Panel Displays

TABLE 33 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE COATINGS IN FIELD EMISSION DEVICES, THROUGH 2012 ($ MILLIONS)

Medical Instruments

TABLE 34 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE COATINGS IN MEDICAL INSTRUMENTS, THROUGH 2012 ($ MILLIONS)

Consumer Applications

TABLE 35 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE COATINGS IN CONSUMER APPLICATIONS, THROUGH 2012 ($ MILLIONS)

Razor Blades

TABLE 36 GLOBAL MARKET FOR DIAMOND-LIKE COATINGS IN RAZOR BLADE APPLICATIONS, THROUGH 2012 ($ MILLIONS)

Camera Lenses and Watch Glasses

TABLE 37 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE COATINGS IN CAMERA LENSES AND WATCH GLASSES, THROUGH 2012 ($ MILLIONS)

Sports Equipment

TABLE 38 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE COATINGS IN SPORTS EQUIPMENT, THROUGH 2012 ($ MILLIONS)

Temperature- and Wear-Resistant Coatings

TABLE 39 GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE TEMPERATURE AND WEAR-RESISTANT COATINGS FOR MILITARY APPLICATIONS, THROUGH 2012 ($ MILLIONS) DIAMOND FILM VERSUS DIAMOND-LIKE FILM

TABLE 40 DIAMOND FILM VS. DIAMOND-LIKE FILM USAGE BY APPLICATION, 2006 ($ MILLION/%)

FIGURE 3 DIAMOND VS. DLC/CBN COATNG MARKET SHARES, 2006 VS. 2012 (%)

GEOGRAPHICAL MARKETS

FIGURE 4 REGIONAL MARKET SHARES FOR DIAMOND, CBN, AND DIAMOND-LIKE THIN FILMS AND COATINGS, 2006 VS. 2012 (% OF TOTAL MARKET)

INDUSTRY STRUCTURE AND COMPETITION U.S. COMPANIES

TABLE 41 U.S. PRODUCERS OF DIAMOND THIN-FILM PRODUCTS

TABLE 42 U.S. SUPPLIERS OF DIAMOND THICK FILMS

TABLE 43 CURRENT AND POTENTIAL U.S. SUPPLIERS OF DIAMOND-DEPOSITION SYSTEMS

INTERNATIONAL COMPETITION

INTERNATIONAL COMPETITION (CONTINUED)

APPENDIX I COMPANY PROFILES ADVANCED TECHNOLOGY MATERIALS, INC ALCATEL-LUCENT AMPLEX SUPERABRASIVES APPLIED SCIENCES, INC. BOEING COMPANY CARO CARBIDE CEMECON GMBH CONTINENTAL INDUSTRIAL DIAMOND, INC CRYSTALLUME, INC. DIAMOND INNOVATIONS, INC. DIAMONEX, INC DUPONT ELEMENT 6, LTD. FLOWSERVE CORP GLOBAL GILLETTE GENERAL MOTORS CORP HARRIS INTERNATIONAL IBM CORP INTEGRATED PACKAGING ASSEMBLY CORP. IONBOND AG KENNAMETAL, INC LOVEJOY TOOL CO., INC. NISU LABORATORIES OERLIKON BALZERS COATING QQC, INC RAYTHEON CO. SIEMENS AG SURFACE CONVERSION TECHNOLOGIES, INC. SURMET TASCON CORP TEXAS INSTRUMENTS, INC. VALENITE, INC. VEECO INSTRUMENTS, INC VERTEX DIAMOND TOOL CO. XEROX CORP.

APPENDIX II OTHER COMPANIES INVOLVED IN DIAMOND AND DIAMONDLIKE FILMS AND COATINGS AEA INDUSTRIAL TECHNOLOGY BAE SYSTEMS CANON, INC. CITIZEN WATCH CO., LTD. DENKI KOGYO CO., LTD DAIMLERCHRYSLER AG DAIMLERCHRYSLER AG FUJITSU LABORATORIES, LTD. HITACHI, LTD HOYA CORP IDEMITSU PETROCHEMICAL CO., LTD. ISHIKAWAJIMA-HARIMA HEAVY INDUSTRIES, LTD JAPAN SYNTHETIC RUBBER CO., LTD KOBE STEEL, LTD. KYOCERA CORP. MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD MITSUBISHI MATERIALS CORP. MITSUI ENGINEERING & SHIPBUILDING CO., LTD. MITSUI MINING CO., LTD. MONSANTO JAPAN, LTD NATIONAL INSTITUTE FOR RESEARCH IN INORGANIC MATERIALS (NIRIM) NATIONAL INSTITUTE OF TECHNOLOGY AND ADVANCED INDUSTRIAL SCIENCE NEC CORP. NKK CORP. (NKK) NIKON CORP NORITAKE DIAMOND INDUSTRIES CO., LTD OKI ELECTRIC INDUSTRY CO., LTD REFMET CEAMICS LTD RICOH CO., LTD. SANDVIK AB SEIKO INSTRUMENTS, INC SHOWA DENKO K.K. SONY CORP SUMITOMO ELECTRIC INDUSTRY, LTD. TEER COATINGS, LTD. TOMEI DIAMOND CO., LTD TOSHIBA CORP. R&D CENTER TOYOTA CRDL, INC. ULVAC, INC VAKUUMTECHNIK GMBH

APPENDIX III U.S.UNIVERSITIES AND INSTITUTIONS INVOLVED IN DIAMOND, CBN, AND DIAMOND-LIKE FILM RESEARCH ARGONNE NATIONAL LABORATORY AUBURN UNIVERSITY CALIFORNIA INSTITUTE OF TECHNOLOGY CASE WESTERN RESERVE UNIVERSITY CITY UNIVERSITY CLARKSON UNIVERSITY CORNELL UNIVERSITY DARPA TACTICAL TECHNOLOGY DREXEL UNIVERSITY ELECTRIC POWER RESEARCH INSTITUTE GEORGIA INSTITUTE OF TECHNOLOGY HARVARD UNIVERSITY LAWRENCE BERKELEY LAB LOS ALAMOS NATIONAL LABORATORY MARSHALL UNIVERSITY MASSACHUSETTS INSTITUTE OF TECHNOLOGY MICHIGAN STATE UNIVERSITY NASA LEWIS RESEARCH CENTER NATIONAL INSTITUTE OF STANDARDS & TECHNOLOGY NAVAL AIR DEVELOPMENT CENTER NAVAL OCEAN SYSTEMS CENTER NAVAL RESEARCH LABORATORY NAVAL WEAPONS CENTER NEW MEXICO INSTITUTE OF TECHNOLOGY NORTH CAROLINA STATE UNIVERSITY NORTHWESTERN UNIVERSITY OAK RIDGE NATIONAL LABORATORY OHIO STATE UNIVERSITY OLIN COLLEGE OF ENGINEERING PENNSYLVANIA STATE UNIVERSITY RESEARCH TRIANGLE INSTITUTE RUTGERS UNIVERSITY SRI INTL. SANDIA NATIONAL LABORATORIES SANDIA NATIONAL LABORATORIES STANFORD UNIVERSITY UNIVERSITY OF ARKANSAS UNIVERSITY OF CENTRAL FLORIDA UNIVERSITY OF CINCINNATI UNIVERSITY OF CINCINNATI UNIVERSITY OF CALIFORNIA, BERKELEY UNIVERSITY OF CALIFORNIA, LOS ANGELES UNIVERSITY OF CONNECTICUT UNIVERSITY OF FLORIDA UNIVERSITY OF LOUISVILLE UNIVERSITY OF MICHIGAN UNIVERSITY OF MINNESOTA UNIVERSITY OF NEBRASKA UNIVERSITY OF NORTH TEXAS UNIVERSITY OF PITTSBURGH UNIVERSITY OF TENNESSEE-KNOXVILLE UNIVERSITY OF TEXAS AT ARLINGTON UNIVERSITY OF TEXAS AT DALLAS UNIVERSITY OF TULSA UNIVERSITY OF UTAH UNIVERSITY OF VIRGINIA VANDERBILT UNIVERSITY WASHINGTON STATE UNIVERSITY WAYNE STATE UNIVERSITY WRIGHT LABORATORY

APPENDIX IV FOREIGN UNIVERSITIES AND INSTITUTIONS INVOLVED IN DIAMOND, CBN, AND DIAMOND-LIKE FILM RESEARCH AICHI UNIVERSITY OF EDUCATION AOYAMA GAKUIN UNIVERSITY BEIJING INSTITUTE OF TECHNOLOGY BEIJING UNIVERSITY OF SCIENCE AND TECHNOLOGY BYELORUSSIAN SSR ACADEMY OF SCIENCE CAMBRIDGE UNIVERSITY CENTRAL INSTITUTE FOR COMPUTER TECHNOLOGIES CHENGDU UNIVERSITY OF SCIENCE AND TECHNOLOGY CHIBA INSTITUTE OF TECHNOLOGY CHIBA UNIVERSITY CHINESE ACADEMY OF SCIENCES CENTER OF SUPER-DIAMOND AND ADVANCED FILMS (COSDAF) COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH ORG. EAST CHINA NORMAL UNIVERSITY EINDHOVEN UNIVERSITY TECHNOLOGY FACHBEREICH PHYSIK FRAUNHOFER INSTITUTE FOR SURFACE ENGINEERING AND THIN FRAUNHOFER INSTITUT FÜR ANGEWANDE FESTKÖRPERPHYSIK FRAUNHOFER INSTITUT FÜR SCHICHT UND OBERFLÄCHENTECHNIK FRAUNHOFER INSTITUT FÜR WERKSTOFFPHYSIK UND GENERAL PHYSICS INSTITUTE HERIOT-WATT UNIVERSITY INDIAN INSTITUTE OF TECHNOLOGY — MUMBAI INSTITUT FUR ANGEWANDTE PHYSIKALISCHE CHEMIE INSTITUTE FOR SUPERHARD MATERIALS INSTITUTE OF ATOMIC AND MOLECULAR PHYSICS INSTITUTE OF MECHNICAL ENGINEERING INSTITUTO NACIONAL DE PESQUISAS ESPACIAIS KHARKOV STATE POLYTECHNICAL UNIVERSITY JAPAN FINE CERAMICS CENTER KING’S COLLEGE OF LONDON KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY LABORATORY OF SOLID LUBRICATION OF CHEMICAL PHYSICS LANZHUO UNIVERSITY MOSCOW STATE UNIVERSITY NAGOYA UNIVERSITY NANJING UNIVERSITY NATIONAL INSTITUTE FOR RESEARCH IN INORGANIC MATERIALS (NIRIM) NATIONAL CHEG KUNG UNIVERSITY NAITONAL INSTITUTE OF MATERIALS SCIENCE NATIONAL SCIENCE CENTRE NATIONAL TAIPEI UNIVERSITY NETHERLANDS ENERGY RESEARCH FOUNDATION NIPPON INSTITUTE OF TECHNOLOGY OSAKA UNIVERSITY PEKING UNIVERSITY RESEARCH INSTITUTE OF SYNTHETIC CRYSTALS RESEARCH INSTITUTE OF SYNTHETIC CRYSTALS ROYAL MELBOURNE INSTITUTE OF TECHNOLOGY RUSSIAN ACADEMY OF SCIENCES RYUKOKU UNIVERSITY SAITAMA UNIVERSITY SARDAR PATEL UNIVERSITY SCIENCE AND TECHNOLOGY AGENCY SCIENCE UNIVERSITY OF TOKYO IN YAMAGUCHI SCONLAND RESEARCH CENTER FOR NUCLEAR SCIENCES SEOUL NATIONAL UNIVERSITY SHANGHAI INSTITUTE OF METALLURGY STATE ENGINEERING UNIVERSITY OF ARMENIA TEACHERS COLLEGE OF RAILWAY IN SUZHOU TECHNICAL RESEARCH CENTER OF FINLAND TECHNISCHE UNIVERSITÄT CHEMNITZ-ZWICKAU TECHNICAL UNIVERSITY OF LODZ TECHNICAL UNIVERSITY OF VIENNA TEIKYO UNIVERSITY OF SCIENCE & TECHNOLOGY TOHOKU UNIVERSITY TOKAI UNIVERSITY TOKYO DENKI UNIVERSITY TOKYO INSTITUTE OF TECHNOLOGY TOYO UNIVERSITY UKRAINE ACADEMY OF SCIENCES UNIVERSITY OF BRISTOL UNIVERSITY OF ELECTROCOMMUNICATIONS UNIVERSITY OF EXETER UNIVERSITY OF GÖTTIGEN UNIVERSITY OF HAMBURG UNIVERSITY OF HEIDELBERG UNIVERSITY OF HELSINKI UNIVERSITY OF KASSEL UNIVERSITY OF LONDON UNIVERSITY OF MELBORNE UNIVERSITY OF PRETORIA UNIVERSITY OF SCIENCE AND TECHNOLOGY UNIVERSITY OF READING UNIVERSITY OF TOKYO UNIVERSITY OF TOKYO UNIVERSITY OF TSUKUBA UNIVERSITY OF THE WITWATERSTRAND UNIVERSITY OF ULM VIENNA TECHNOLOGICAL UNIVERSITY WARSAW UNIVERSITY OF TECHNOLOGY WARSAW UNIVERSITY OF TECHNOLOGY

ENDNOTES

LIST OF TABLES

SUMMARY TABLE GLOBAL MARKET FOR DIAMOND AND DIAMOND-LIKE COATINGS, THROUGH 2012 ($ MILLION)

TABLE 1 PROPERTIES OF POLYCRYSTALLINE DIAMOND AND DIAMOND-LIKE FILMS COMPARED TO NATURAL DIAMOND

TABLE 2 CHARACTERISTICS OF CVD DIAMOND FILM

TABLE 3 PROPERTIES OF DIAFILM OPTICAL-GRADE POLYCRYSTALLINE DIAMOND MATERIAL SUPPLIED BY HARRIS INTERNATIONAL

TABLE 4 PROPERTIES OF CVD POLYCRYSTALLINE DIAMOND MATERIAL FOR THERMAL MANAGEMENT SUBSTRATES

TABLE 5 COMPARISON OF PROPERTIES: NATURAL, PCD/CVD DIAMONDS, AND DIAMOND-LIKE CARBON FILMS

TABLE 6 ADVANTAGES OF CVD DIAMOND

TABLE 7 DISADVANTAGES OF CVD DIAMOND

TABLE 8 CURRENT PROCESSING TECHNOLOGIES FOR THIN AND THICK DIAMOND FILMS

TABLE 9 PLASMA-ENHANCED CHEMICAL VAPOR DEPOSITION (PECVD) PROCESSES FOR DIAMOND FILM GROWTH

TABLE 10 NONPLASMA DEPOSITION PROCESSES FOR DIAMOND FILM GROWTH (MICRONS/HR)

TABLE 11 DEPOSITION DATA FOR DLC, BN, AND RELATED COMPOSITES

TABLE 12 CURRENT PROCESSING TECHNOLOGIES FOR DIAMOND-LIKE THIN FILMS

TABLE 13 CURRENT PROCESSING TECHNOLOGIES FOR CBN FILMS

TABLE 14 CVD DIAMOND AND DLC APPLICATIONS

TABLE 15 PROPERTIES OF DIAMOND TOOL MATERIALS, C-2 TUNGSTEN CARBIDE, AND SILICON NITRIDE

TABLE 16 COMPARISON OF PROPERTIES OF DIAMOND AND OTHER SEMICONDUCTOR MATERIALS

TABLE 17 FIGURES OF MERIT FOR THERMAL STRESS RESISTANCE

TABLE 18 DIAMOND-LIKE FILM APPLICATIONS

TABLE 19 CURRENT APPLICATIONS FOR HYDROGENATED DLC

TABLE 20 GLOBAL MARKET FOR DIAMOND AND DIAMONDLIKE COATINGS BY APPLICATION SEGMENT, THROUGH 2012 ($ MILLION)

TABLE 21 GLOBAL MARKET FOR DIAMOND AND DIAMONDLIKE FILM IN TOOLS AND WEAR-RESISTANT PARTS, THROUGH 2012 ($ MILLIONS)

TABLE 22 GLOBAL CONSUMPTION OF DIAMOND AND DIAMOND-LIKE COATINGS FOR CUTTING TOOL INSERTS, 2006 ($ MILLION)